Only if the DOCX has a real text layer. Table extraction reads text and its position on the page; a scan is a picture of a page, so there is nothing to read. Run OCR on it first, then convert the searchable result to XLSX.
װעט מײַן XLSX װײַזן זיך ווי דער טאַבעלע אין DOCX?
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It will hold the same values in the same rows and columns, but not the same styling. Colours, fonts and borders are dropped and merged cells are flattened out; the point of the XLSX is the data, which you can then format however you like.
